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Synthesis and thermal stability of cubic ZnO in the salt nanocomposites

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Abstract

Cubic zinc oxide (rs-ZnO), metastable under normal conditions, was synthesized from the wurtzite modification (w-ZnO) at 7.7 GPa and ∼800 K in the form of nanoparticles isolated in the NaCl matrix. The phase transition rs-ZnO → w-ZnO in nanocrystalline zinc oxide under ambient pressure was experimentally studied for the first time by using differential scanning calorimetry and high-temperature X-ray diffraction analysis. It was shown that the transition occurs in the temperature range from 370 to 430 K and its enthalpy at 400 K is −10.2 ± 0.5 kJ mol−1.

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Authors and Affiliations

  1. Laboratory of Mechanical and Thermodynamic Properties of Materials, LPMTM-CNRS, Université Paris 13, 99 avenue J. B. Clément, 93430, Villetaneuse, France

    P. S. Sokolov & V. L. Solozhenko

  2. Department of Materials Science, M. V. Lomonosov Moscow State University, 1 Leninskie gory, 119991, Moscow, Russian Federation

    P. S. Sokolov

  3. Department of Chemistry, M. V. Lomonosov Moscow State University, 1 Leninskie gory, 119991, Moscow, Russian Federation

    A. N. Baranov

  4. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation

    Zh. V. Dobrokhotov

Authors
  1. P. S. Sokolov
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  2. A. N. Baranov
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  3. Zh. V. Dobrokhotov
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  4. V. L. Solozhenko
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Correspondence to A. N. Baranov.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 318–321, February, 2010.

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Sokolov, P.S., Baranov, A.N., Dobrokhotov, Z.V. et al. Synthesis and thermal stability of cubic ZnO in the salt nanocomposites. Russ Chem Bull 59, 325–328 (2010). https://doi.org/10.1007/s11172-010-0082-7

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  • DOI: https://doi.org/10.1007/s11172-010-0082-7

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